Fiket Željka, Rožmarić Martina, Krmpotić Matea, Benedik Ljudmila
Division for Marine and Environmental Research, Ruđer Bošković Institute, Bijenička cesta 54, 10000, Zagreb, Croatia,
Environ Sci Pollut Res Int. 2015 May;22(9):6789-99. doi: 10.1007/s11356-014-3869-5. Epub 2014 Nov 29.
Concentrations of 46 elements, including major, trace, and rare earth elements, and (238)U in Croatian tap waters were investigated. Selected sampling locations include tap waters from various hydrogeological regions, i.e., different types of aquifers, providing insight into the range of concentrations of studied elements and (238)U activity concentrations in Croatian tap waters. Obtained concentrations were compared with the Croatian maximum contaminant levels for trace elements in water intended for human consumption, as well as WHO and EPA drinking water standards. Concentrations in all analyzed tap waters were found in accordance with Croatian regulations, except tap water from Šibenik in which manganese in concentration above maximum permissible concentration (MPC) was measured. Furthermore, in tap water from Osijek, levels of arsenic exceeded the WHO guidelines and EPA regulations. In general, investigated tap waters were found to vary considerably in concentrations of studied elements, including (238)U activity concentrations. Causes of variability were further explored using statistical methods. Composition of studied tap waters was found to be predominately influenced by hydrogeological characteristics of the aquifer, at regional and local level, the existing redox conditions, and the household plumbing system. Rare earth element data, including abundances and fractionation patterns, complemented the characterization and facilitated the interpretation of factors affecting the composition of the analyzed tap waters.
对克罗地亚自来水(包括常量元素、微量元素、稀土元素以及(238)U)中的46种元素浓度进行了调查。选定的采样地点包括来自不同水文地质区域(即不同类型含水层)的自来水,从而深入了解克罗地亚自来水中所研究元素的浓度范围以及(238)U活度浓度。将获得的浓度与克罗地亚供人类消费的水中微量元素的最大污染物水平以及世界卫生组织(WHO)和美国环境保护局(EPA)的饮用水标准进行了比较。除了希贝尼克的自来水检测到锰浓度高于最大允许浓度(MPC)外,所有分析的自来水中的浓度均符合克罗地亚法规。此外,在奥西耶克的自来水中,砷含量超过了世界卫生组织的指导方针和美国环境保护局的规定。总体而言,研究发现所调查的自来水中所研究元素的浓度(包括(238)U活度浓度)差异很大。使用统计方法进一步探讨了变异性的原因。研究发现,所研究的自来水成分在区域和地方层面主要受含水层的水文地质特征、现有的氧化还原条件以及家庭管道系统的影响。稀土元素数据(包括丰度和分馏模式)补充了特征描述,并有助于解释影响所分析自来水成分的因素。