Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032 (China).
Angew Chem Int Ed Engl. 2015 Jan 19;54(4):1270-4. doi: 10.1002/anie.201409617. Epub 2014 Dec 2.
An efficient palladium-catalyzed Heck-type reaction of fluoroalkyl halides, including perfluoroalkyl bromides, trifluoromethyl iodides, and difluoroalkyl bromides, has been developed. The reaction proceeds under mild reaction conditions with high efficiency and broad substrate scope, and provides a general and straightforward access to fluoroalkylated alkenes which are of interest in life and material sciences.
发展了一种高效的钯催化卤代氟烷基（包括全氟烷基溴、三氟甲基碘和二氟烷基溴）的 Heck 型反应。该反应在温和的反应条件下以高效率和广泛的底物范围进行，并为生命和材料科学中感兴趣的氟烷基化烯烃提供了一种通用且直接的方法。
