College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang, Henan 464000, China.
Chem Commun (Camb). 2020 Aug 21;56(65):9384-9387. doi: 10.1039/c9cc10048b. Epub 2020 Jul 16.
Herein, we report a palladium-catalyzed relay Heck-type reaction of fluoroalkyl bromide and terminal alkenes. The reaction involves fluoroalkylation of alkenes and migration of double bonds via a 1,5-hydrogen atom transfer strategy. Through this method, a series of remote fluoroalkylated alkenes was obtained under mild conditions.
在此，我们报告了钯催化的氟烷基溴和末端烯烃的接力 Heck 型反应。该反应涉及烯烃的氟烷基化和通过 1,5-氢原子转移策略的双键迁移。通过这种方法，在温和条件下得到了一系列远程氟烷基化的烯烃。
