用于快速合成铜-N-杂环卡宾配合物的电化学流动反应器。
Electrochemical flow-reactor for expedient synthesis of copper-N-heterocyclic carbene complexes.
作者信息
Chapman Michael R, Shafi Yarseen M, Kapur Nikil, Nguyen Bao N, Willans Charlotte E
机构信息
School of Chemistry, University of Leeds, Woodhouse Lane, Leeds, LS2 9JT, UK.
出版信息
Chem Commun (Camb). 2015 Jan 25;51(7):1282-4. doi: 10.1039/c4cc08874c.
PMID:25476754
Abstract
An electrochemical flow-cell for highly efficient and selective generation of Cu(I)-N-heterocyclic carbene complexes under neutral and ambient conditions is reported. The feasibility of the flow-cell is demonstrated through the electrochemical synthesis of [Cu(IMes)Cl] and subsequent in situ flow directly into hydrosilylation reactions, with equal efficiency to the purified catalyst.
摘要
报道了一种用于在中性和环境条件下高效、选择性地生成Cu(I)-N-杂环卡宾配合物的电化学流通池。通过电化学合成[Cu(IMes)Cl]并随后原位直接流入硅氢化反应，证明了该流通池的可行性，其效率与纯化后的催化剂相当。
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