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顺应性固体中液体包裹体的表面张力与力学

Surface tension and the mechanics of liquid inclusions in compliant solids.

作者信息

Style Robert W, Wettlaufer John S, Dufresne Eric R

机构信息

Yale University, New Haven, CT 06520, USA.

出版信息

Soft Matter. 2015 Jan 28;11(4):672-9. doi: 10.1039/c4sm02413c. Epub 2014 Dec 12.

DOI:10.1039/c4sm02413c
PMID:25503573
Abstract

Eshelby's theory of inclusions has wide-reaching implications across the mechanics of materials and structures including the theories of composites, fracture, and plasticity. However, it does not include the effects of surface stress, which has recently been shown to control many processes in soft materials such as gels, elastomers and biological tissue. To extend Eshelby's theory of inclusions to soft materials, we consider liquid inclusions within an isotropic, compressible, linear-elastic solid. We solve for the displacement and stress fields around individual stretched inclusions, accounting for the bulk elasticity of the solid and the surface tension (i.e. isotropic strain-independent surface stress) of the solid-liquid interface. Surface tension significantly alters the inclusion's shape and stiffness as well as its near- and far-field stress fields. These phenomena depend strongly on the ratio of the inclusion radius, R, to an elastocapillary length, L. Surface tension is significant whenever inclusions are smaller than 100L. While Eshelby theory predicts that liquid inclusions generically reduce the stiffness of an elastic solid, our results show that liquid inclusions can actually stiffen a solid when R<3L/2. Intriguingly, surface tension cloaks the far-field signature of liquid inclusions when R=3L/2. These results are have far-reaching applications from measuring local stresses in biological tissue, to determining the failure strength of soft composites.

摘要

埃舍尔比夹杂理论在材料与结构力学领域有着广泛的影响,涵盖了复合材料、断裂和塑性理论等。然而,该理论并未考虑表面应力的影响,而最近的研究表明,表面应力控制着诸如凝胶、弹性体和生物组织等软材料中的许多过程。为了将埃舍尔比夹杂理论扩展到软材料,我们考虑了各向同性、可压缩、线弹性固体中的液体夹杂。我们求解了单个拉伸夹杂周围的位移和应力场,同时考虑了固体的体积弹性和固液界面的表面张力(即与应变无关的各向同性表面应力)。表面张力显著改变了夹杂的形状、刚度及其近场和远场应力场。这些现象强烈依赖于夹杂半径R与弹性毛细长度L的比值。当夹杂小于100L时,表面张力的影响显著。虽然埃舍尔比理论预测液体夹杂通常会降低弹性固体的刚度,但我们的结果表明,当R<3L/2时,液体夹杂实际上会使固体变硬。有趣的是,当R = 3L/2时,表面张力掩盖了液体夹杂的远场特征。这些结果在测量生物组织中的局部应力以及确定软复合材料的破坏强度等方面有着广泛的应用。

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