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由内掺杂铁原子稳定的类富勒烯硼簇:n = 14、16、18和20的B(n)Fe

Fullerene-like boron clusters stabilized by an endohedrally doped iron atom: B(n)Fe with n = 14, 16, 18 and 20.

作者信息

Tam Nguyen Minh, Pham Hung Tan, Duong Long Van, Pham-Ho My Phuong, Nguyen Minh Tho

机构信息

Institute for Computational Science and Technology (ICST), Ho Chi Minh City, Vietnam.

出版信息

Phys Chem Chem Phys. 2015 Feb 7;17(5):3000-3. doi: 10.1039/c4cp04279d. Epub 2015 Jan 5.

DOI:10.1039/c4cp04279d
PMID:25557191
Abstract

Stabilized fullerene and tubular forms can be produced in boron clusters Bn in small sizes from n∼ 14 to 20 upon doping by transition metal atoms. B14Fe and B16Fe are stable tubes whereas B18Fe and B20Fe are stable fullerenes. Their formation and stability suggest the use of dopants to induce different growth paths leading to larger cages, fullerenes and tubes of boron.

摘要

通过过渡金属原子掺杂,在尺寸较小(n约为14至20)的硼簇Bn中可以生成稳定的富勒烯和管状结构。B14Fe和B16Fe是稳定的管状物,而B18Fe和B20Fe是稳定的富勒烯。它们的形成和稳定性表明可利用掺杂剂诱导不同的生长路径,从而形成更大的硼笼、富勒烯和硼管。

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