Gernert Robert, Emary Clive, Klapp Sabine H L
Institut für Theoretische Physik, Sekr. EW 7-1, Technische Universität Berlin, Hardenbergstrasse 36, D-10623 Berlin, Germany.
Department of Physics and Mathematics, University of Hull, Kingston-upon-Hull, HU6 7RX, United Kingdom.
Phys Rev E Stat Nonlin Soft Matter Phys. 2014 Dec;90(6):062115. doi: 10.1103/PhysRevE.90.062115. Epub 2014 Dec 8.
The waiting time distribution (WTD) is a common tool for analyzing discrete stochastic processes in classical and quantum systems. However, there are many physical examples where the dynamics is continuous and only approximately discrete, or where it is favourable to discuss the dynamics on a discretized and a continuous level in parallel. An example is the hindered motion of particles through potential landscapes with barriers. In the present paper we propose a consistent generalization of the WTD from the discrete case to situations where the particles perform continuous barrier crossing characterized by a finite duration. To this end, we introduce a recipe to calculate the WTD from the Fokker-Planck (Smoluchowski) equation. In contrast to the closely related first passage time distribution (FPTD), which is frequently used to describe continuous processes, the WTD contains information about the direction of motion. As an application, we consider the paradigmatic example of an overdamped particle diffusing through a washboard potential. To verify the approach and to elucidate its numerical implications, we compare the WTD defined via the Smoluchowski equation with data from direct simulation of the underlying Langevin equation and find full consistency provided that the jumps in the Langevin approach are defined properly. Moreover, for sufficiently large energy barriers, the WTD defined via the Smoluchowski equation becomes consistent with that resulting from the analytical solution of a (two-state) master equation model for the short-time dynamics developed previously by us [Phys. Rev. E 86, 061135 (2012)]. Thus, our approach "interpolates" between these two types of stochastic motion. We illustrate our approach for both symmetric systems and systems under constant force.
等待时间分布(WTD)是分析经典和量子系统中离散随机过程的常用工具。然而,在许多物理实例中,动力学是连续的,只是近似离散,或者在离散和连续层面上并行讨论动力学更为有利。一个例子是粒子在具有势垒的势场中受阻运动。在本文中,我们提出了一种将WTD从离散情况一致推广到粒子进行以有限持续时间为特征的连续势垒穿越情况的方法。为此,我们引入了一种从福克 - 普朗克(斯莫卢霍夫斯基)方程计算WTD的方法。与常用于描述连续过程的密切相关的首次通过时间分布(FPTD)不同,WTD包含有关运动方向的信息。作为应用,我们考虑过阻尼粒子在搓板势中扩散的典型例子。为了验证该方法并阐明其数值含义,我们将通过斯莫卢霍夫斯基方程定义的WTD与基础朗之万方程的直接模拟数据进行比较,发现只要朗之万方法中的跳跃定义得当,就会完全一致。此外,对于足够大的能量势垒,通过斯莫卢霍夫斯基方程定义的WTD与我们之前 [《物理评论E》86, 061135 (2012)] 为短时间动力学开发的(双态)主方程模型的解析解所得到的WTD一致。因此,我们的方法在这两种类型的随机运动之间进行“插值”。我们针对对称系统和恒力作用下的系统说明了我们的方法。