Luo Dongxiang, Xu Hua, Zhao Mingjie, Li Min, Xu Miao, Zou Jianhua, Tao Hong, Wang Lei, Peng Junbiao
Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology , Guangzhou 510640, People's Republic of China.
ACS Appl Mater Interfaces. 2015 Feb 18;7(6):3633-40. doi: 10.1021/am5079682. Epub 2015 Feb 4.
Amorphous indium-gallium-zinc-oxide thin film transistors (α-IGZO TFTs) with damage-free back channel wet-etch (BCE) process were achieved by introducing a carbon nanofilm as a barrier layer. We investigate the effects of different source-and-drain (S/D) materials on TFT performance. We find the TFT with Ti/C S/D electrodes exhibits a superior performance with higher output current, lower threshold voltage, and higher effective electron mobility compared to that of Mo/C S/D electrodes. Transmittance electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS) are employed to analysis the interfacial interaction between S/D metal/C/α-IGZO layers. The results indicate that the better performance of TFTs with Ti/C electrodes should be attributed to the formations of Ti-C and Ti-O at the Ti/C-contact regions, which lead to a lower contact resistance, whereas Mo film is relatively stable and does not react easily with C nanofilm, resulting in a nonohmic contact behavior between Mo/C and α-IGZO layer. However, both kinds of α-IGZO TFTs show good stability under thermal bias stress, indicating that the inserted C nanofilms could avoid the impact on the α-IGZO channel regions during S/D electrodes formation. Finally, we successfully fabricated a high-definition active-matrix organic lighting emitting diode prototype driven by α-IGZO TFTs with Ti/C electrodes in a pilot line.
通过引入碳纳米膜作为阻挡层,实现了具有无损伤背沟道湿法蚀刻(BCE)工艺的非晶铟镓锌氧化物薄膜晶体管(α-IGZO TFT)。我们研究了不同源漏(S/D)材料对TFT性能的影响。我们发现,与Mo/C S/D电极相比,具有Ti/C S/D电极的TFT表现出优异的性能,具有更高的输出电流、更低的阈值电压和更高的有效电子迁移率。采用透射电子显微镜(TEM)和X射线光电子能谱(XPS)分析S/D金属/C/α-IGZO层之间的界面相互作用。结果表明,具有Ti/C电极的TFT性能更好应归因于Ti/C接触区域形成了Ti-C和Ti-O,这导致了更低的接触电阻,而Mo膜相对稳定,不易与碳纳米膜反应,导致Mo/C与α-IGZO层之间呈现非欧姆接触行为。然而,两种α-IGZO TFT在热偏置应力下均表现出良好的稳定性,这表明插入的碳纳米膜可以避免在形成S/D电极期间对α-IGZO沟道区域产生影响。最后,我们在中试生产线中成功制造了由具有Ti/C电极的α-IGZO TFT驱动的高清有源矩阵有机发光二极管原型。