Hennig Andreas, Dietrich Paul M, Hemmann Felix, Thiele Thomas, Borcherding Heike, Hoffmann Angelika, Schedler Uwe, Jäger Christian, Resch-Genger Ute, Unger Wolfgang E S
BAM Federal Institute for Materials Research and Testing, Richard-Willstaetter-Strasse 11, 12203 Berlin, Germany.
Analyst. 2015 Mar 21;140(6):1804-8. doi: 10.1039/c4an02248c. Epub 2015 Feb 5.
The fluorine content of polymer particles labelled with 2,2,2-trifluoroethylamine was reliably quantified with overlapping sensitivity ranges by XPS and solid-state NMR. This provides a first step towards reference materials for the metrological traceability of surface group quantifications. The extension of this concept to fluorescence spectroscopy is illustrated.