Chen Xin, Li Xu, Chen Xiao-Lan, Qu Ling-Bo, Chen Jian-Yu, Sun Kai, Liu Zhi-Dong, Bi Wen-Zhu, Xia Ying-Ya, Wu Hai-Tao, Zhao Yu-Fen
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou City, China.
Chem Commun (Camb). 2015 Mar 4;51(18):3846-9. doi: 10.1039/c4cc10312b.
A highly efficient one-pot strategy has been developed for the synthesis of β-ketophosphonates directly from alkynes and dialkyl H-phosphonates in the presence of widely available AgNO3/CuSO4 and K2S2O8 at room temperature under open-air conditions.
已开发出一种高效的一锅法策略,用于在室温露天条件下,在广泛可得的硝酸银/硫酸铜和过硫酸钾存在下,直接由炔烃和二烷基H-膦酸酯合成β-酮膦酸酯。