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涂覆有酚离子络合物的纳米金刚石中单个氮空位缺陷的增强光致发光。

Enhanced photoluminescence from single nitrogen-vacancy defects in nanodiamonds coated with phenol-ionic complexes.

作者信息

Bray Kerem, Previdi Rodolfo, Gibson Brant C, Shimoni Olga, Aharonovich Igor

机构信息

School of Physics and Advanced Materials, University of Technology, Sydney, P.O. Box 123, Broadway, New South Wales 2007, Australia.

出版信息

Nanoscale. 2015 Mar 21;7(11):4869-74. doi: 10.1039/c4nr07510b.

Abstract

Fluorescent nanodiamonds are attracting major attention in the field of bio-sensing and bio-labeling. In this work we demonstrate a robust approach to achieve an encapsulation of individual nanodiamonds with phenol-ionic complexes that enhance the photoluminescence from single nitrogen vacancy (NV) centers. We show that single NV centres in the coated nanodiamonds also exhibit shorter lifetimes, opening another channel for high resolution sensing. We propose that the nanodiamond encapsulation reduces the non-radiative decay pathways of the NV color centers. Our results provide a versatile and assessable way to enhance photoluminescence from nanodiamond defects that can be used in a variety of sensing and imaging applications.

摘要

荧光纳米金刚石在生物传感和生物标记领域正引起广泛关注。在这项工作中,我们展示了一种稳健的方法,通过酚离子络合物实现对单个纳米金刚石的封装,从而增强单个氮空位(NV)中心的光致发光。我们表明,包覆后的纳米金刚石中的单个NV中心还具有更短的寿命,为高分辨率传感开辟了另一条途径。我们认为纳米金刚石封装减少了NV色心的非辐射衰变途径。我们的结果提供了一种通用且可行的方法来增强纳米金刚石缺陷的光致发光,可用于各种传感和成像应用。

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