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受限硬环境中的软物质:纳米多孔介质中的相变热力学、结构、织构、扩散与流动

Soft matter in hard confinement: phase transition thermodynamics, structure, texture, diffusion and flow in nanoporous media.

作者信息

Huber Patrick

机构信息

Hamburg University of Technology (TUHH), Institute of Materials Physics and Technology, Eißendorfer Str. 42, D-21073 Hamburg-Harburg (Germany.

出版信息

J Phys Condens Matter. 2015 Mar 18;27(10):103102. doi: 10.1088/0953-8984/27/10/103102. Epub 2015 Feb 13.

Abstract

Spatial confinement in nanoporous media affects the structure, thermodynamics and mobility of molecular soft matter often markedly. This article reviews thermodynamic equilibrium phenomena, such as physisorption, capillary condensation, crystallisation, self-diffusion, and structural phase transitions as well as selected aspects of the emerging field of spatially confined, non-equilibrium physics, i.e. the rheology of liquids, capillarity-driven flow phenomena, and imbibition front broadening in nanoporous materials. The observations in the nanoscale systems are related to the corresponding bulk phenomenologies. The complexity of the confined molecular species is varied from simple building blocks, like noble gas atoms, normal alkanes and alcohols to liquid crystals, polymers, ionic liquids, proteins and water. Mostly, experiments with mesoporous solids of alumina, gold, carbon, silica, and silicon with pore diameters ranging from a few up to 50 nm are presented. The observed peculiarities of nanopore-confined condensed matter are also discussed with regard to applications. A particular emphasis is put on texture formation upon crystallisation in nanoporous media, a topic both of high fundamental interest and of increasing nanotechnological importance, e.g. for the synthesis of organic/inorganic hybrid materials by melt infiltration, the usage of nanoporous solids in crystal nucleation or in template-assisted electrochemical deposition of nano structures.

摘要

纳米多孔介质中的空间限制常常会显著影响分子软物质的结构、热力学和流动性。本文综述了物理吸附、毛细凝聚、结晶、自扩散和结构相变等热力学平衡现象,以及空间限制非平衡物理学这一新兴领域的某些方面,即液体的流变学、毛细驱动流动现象以及纳米多孔材料中的吸渗前沿展宽。纳米尺度系统中的观测结果与相应的体相现象学相关。受限分子种类的复杂性从简单的构建单元,如稀有气体原子、正构烷烃和醇类,到液晶、聚合物、离子液体、蛋白质和水不等。本文主要介绍了孔径从几纳米到50纳米不等的氧化铝、金、碳、二氧化硅和硅等介孔固体的实验。还讨论了纳米孔受限凝聚态物质的观测特性在应用方面的情况。特别强调了纳米多孔介质中结晶时的织构形成,这一主题既具有很高的基础研究价值,在纳米技术中的重要性也日益增加,例如通过熔体渗透合成有机/无机杂化材料、在晶体成核中使用纳米多孔固体或在纳米结构的模板辅助电化学沉积中使用纳米多孔固体。

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