Nabeel Muhammad Ikram, Hussain Dilshad, Ahmad Naseer, Najam-Ul-Haq Muhammad, Musharraf Syed Ghulam
HEJ Research Institute of Chemistry, International Center for Chemical and Biological Sciences, University of Karachi Karachi-75270 Pakistan
Institute of Chemical Sciences, Bahauddin Zakariya University Multan 60800 Pakistan.
Nanoscale Adv. 2023 Aug 21;5(19):5214-5255. doi: 10.1039/d3na00159h. eCollection 2023 Sep 26.
The present review focuses on the widely used graphitic carbon nitride (g-CN)-tungsten oxide (WO) nanocomposite in photocatalytic applications. These catalysts are widely employed due to their easy preparation, high physicochemical stability, nontoxicity, electron-rich properties, electronic band structure, chemical stability, low cost, earth-abundance, high surface area, and strong absorption capacity in the visible range. These sustainable properties make them predominantly attractive and unique from other photocatalysts. In addition, graphitic carbon nitride (g-CN) is synthesized from nitrogen-rich precursors; therefore, it is stable in strong acid solutions and has good thermal stability up to 600 °C. This review covers the historical background, crystalline phases, density-functional theory (DFT) study, synthesis method, 0-D, 1-D, 2-D, and 3-D materials, oxides/transition/nontransition metal-doped, characterization, and photocatalytic applications of WO/g-CN. Enhancing the catalytic performance strategies such as composite formation, element-doping, heterojunction construction, and nanostructure design are also summarized. Finally, the future perspectives and challenges for WO/g-CN composite materials are discussed to motivate young researchers and scientists interested in developing environment-friendly and efficient catalysts.
本综述聚焦于光催化应用中广泛使用的石墨相氮化碳(g-CN)-氧化钨(WO)纳米复合材料。这些催化剂因其易于制备、高物理化学稳定性、无毒、富电子特性、电子能带结构、化学稳定性、低成本、储量丰富、高比表面积以及在可见光范围内的强吸收能力而被广泛应用。这些可持续特性使它们相较于其他光催化剂具有显著的吸引力和独特性。此外,石墨相氮化碳(g-CN)由富氮前驱体合成;因此,它在强酸溶液中稳定,在高达600°C的温度下具有良好的热稳定性。本综述涵盖了WO/g-CN的历史背景、晶相、密度泛函理论(DFT)研究、合成方法、0维、1维、2维和3维材料、氧化物/过渡/非过渡金属掺杂、表征以及光催化应用。还总结了提高催化性能的策略,如复合形成、元素掺杂、异质结构建和纳米结构设计。最后,讨论了WO/g-CN复合材料的未来前景和挑战,以激励对开发环境友好且高效催化剂感兴趣的年轻研究人员和科学家。