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吡蚜酮纳米制剂在秋葵(黄秋葵[L] 莫恩奇)中的残留、消解及安全性评价。

Residue, dissipation, and safety evaluation of pyridalyl nanoformulation in Okra (Abelmoschus esculentus [L] Moench).

作者信息

Saini Priya, Gopal Madhuban, Kumar Rajesh, Gogoi Robin

机构信息

Division of Agricultural Chemicals, Indian Agricultural Research Institute, New Delhi, 110012, India.

出版信息

Environ Monit Assess. 2015 Mar;187(3):123. doi: 10.1007/s10661-015-4361-5. Epub 2015 Feb 20.

Abstract

A comparative study on residues and rate of dissipation of a new nanoformulation of pyridalyl and commercial pyridalyl was carried out on okra under net house and field conditions. Okra crop was sprayed with commercial and nanoformulation of pyridalyl at recommended (75 g a. i./ha) and double the recommended dose (150 g a. i./ha) at the time of fruiting. Quantitation of residues of pyridalyl in okra was done by ultra high performance liquid chromatography over a period of 15 days, and recovery of the method ranged from 79 to 87 %. The half life calculated from the dissipation pattern of pyridalyl on okra for commercial and developed nanoformulation proved that residues of nanopyridalyl did not persist much longer than that of conventional formulation in net house as well as in field trials. The risk quotient value of pyridalyl in okra was significantly lower than 1, implying its negligible risk to the humans.

摘要

在网室和田间条件下,对新型吡蚜酮纳米制剂和市售吡蚜酮在秋葵上的残留量及消解速率进行了比较研究。在结果期,用市售和纳米制剂吡蚜酮以推荐剂量(75克有效成分/公顷)和两倍推荐剂量(150克有效成分/公顷)对秋葵作物进行喷雾处理。采用超高效液相色谱法在15天内对秋葵中吡蚜酮的残留量进行定量分析,该方法的回收率在79%至87%之间。根据市售和研发的纳米制剂中吡蚜酮在秋葵上的消解模式计算出的半衰期表明,在网室和田间试验中,纳米吡蚜酮的残留时间并不比传统制剂长得多。秋葵中吡蚜酮的风险商值显著低于1,这意味着其对人类的风险可忽略不计。

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