首个水溶性主链钌-钌-镍异金属有机金属聚合物。
First water-soluble backbone Ru-Ru-Ni heterometallic organometallic polymer.
作者信息
Scalambra Franco, Serrano-Ruiz Manuel, Romerosa Antonio
机构信息
Área de Química Inorgánica-CIESOL, Universidad de Almería, 04120, Almería, Spain.
出版信息
Macromol Rapid Commun. 2015 Apr;36(7):689-93. doi: 10.1002/marc.201400657. Epub 2015 Mar 4.
The water-soluble backbone heterometallic polymer {[(PTA)2 CpRu-μ-CN-RuCp(PTA)2 -μ-NiCl3 ]}n (2) is synthesized using a reproducible and robust method and fully characterized by X-ray single crystal diffraction. The Ru-Ru-Ni polymer is found to be stable in the solid state and soluble in water. Nuclear magnetic resonance (NMR) and light scattering studies show that the polymer is stable in water for several days in air.
水溶性主链异金属聚合物{[(PTA)2 CpRu-μ-CN-RuCp(PTA)2 -μ-NiCl3 ]}n (2)采用一种可重复且可靠的方法合成，并通过X射线单晶衍射进行了全面表征。发现钌-钌-镍聚合物在固态下稳定且可溶于水。核磁共振（NMR）和光散射研究表明，该聚合物在空气中于水中可稳定存在数天。
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