Chane Camille Simon, Thoury Mathieu, Tournié Aurélie, Echard Jean-Philippe
Musée de la musique, Equipe Conservation Recherche, Cité de la musique, 221 avenue Jean Jaurè s, 75019 Paris, France.
Appl Spectrosc. 2015 Apr;69(4):430-41. doi: 10.1366/14-07554. Epub 2015 Mar 1.
Luminescence multispectral imaging is a developing and promising technique in the fields of conservation science and cultural heritage studies. In this article, we present a new methodology for recording the spatially resolved luminescence properties of objects. This methodology relies on the development of a lab-made multispectral camera setup optimized to collect low-yield luminescence images. In addition to a classic data preprocessing procedure to reduce noise on the data, we present an innovative method, based on a neural network algorithm, that allows us to obtain radiometrically calibrated luminescence spectra with increased spectral resolution from the low-spectral resolution acquisitions. After preliminary corrections, a neural network is trained using the 15-band multispectral luminescence acquisitions and corresponding spot spectroscopy luminescence data. This neural network is then used to retrieve a megapixel multispectral cube between 460 and 710 nm with a 5 nm resolution from a low-spectral-resolution multispectral acquisition. The resulting data are independent from the detection chain of the imaging system (filter transmittance, spectral sensitivity of the lens and optics, etc.). As a result, the image cube provides radiometrically calibrated emission spectra with increased spectral resolution. For each pixel, we can thus retrieve a spectrum comparable to those obtained with conventional luminescence spectroscopy. We apply this method to a panel of lake pigment paints and discuss the pertinence and perspectives of this new approach.
发光多光谱成像是保护科学和文化遗产研究领域中一项正在发展且颇具前景的技术。在本文中,我们提出了一种记录物体空间分辨发光特性的新方法。该方法依赖于开发一种实验室自制的多光谱相机装置,该装置经过优化以收集低产率发光图像。除了用于减少数据噪声的经典数据预处理程序外,我们还提出了一种基于神经网络算法的创新方法,该方法使我们能够从低光谱分辨率采集中获得具有更高光谱分辨率的辐射校准发光光谱。经过初步校正后,使用15波段多光谱发光采集数据和相应的点光谱发光数据训练神经网络。然后,该神经网络用于从低光谱分辨率多光谱采集中检索分辨率为5nm、波长范围在460至710nm之间的百万像素多光谱立方体。所得数据独立于成像系统的检测链(滤光片透过率、镜头和光学器件的光谱灵敏度等)。因此,图像立方体提供了具有更高光谱分辨率的辐射校准发射光谱。对于每个像素,我们都可以检索到与传统发光光谱法获得的光谱相当的光谱。我们将此方法应用于一组湖泊颜料涂料,并讨论了这种新方法的相关性和前景。