Glazer A M
Clarendon Laboratory, Parks Road, Oxford OX1 3PU, UK
Philos Trans A Math Phys Eng Sci. 2015 Apr 13;373(2039). doi: 10.1098/rsta.2014.0232.
Prof. Dame Kathleen Lonsdale was one of the two first female Fellows of the Royal Society, having originally been a student of that great British scientist and Nobel Laureate William Henry Bragg. She came to fame initially for her solution of the crystal structure of hexamethyl benzene, thus demonstrating that the benzene ring was flat, of considerable importance to organic chemistry, where it had been proposed before but without proof. This was at a time when the solution of crystal structures was in its infancy, and in its day this work was considered a triumph. As a rare example then of a female physicist, Lonsdale became interested in various aspects of the diffraction of X-rays, and in particular published an important paper on a form of diffraction in which a strongly divergent source was used rather than the usual highly collimated beam. The photographs thus obtained showed a series of arcs and circles, whose positions were so sensitive that they could be used to determine the quality of crystals such as diamond, and even to calculate their lattice dimensions, and hence carbon-carbon bond lengths, to hitherto extraordinary precision. Lonsdale also became known not just as a scientist but as a peace activist and an active member of the Society of Friends. This commentary was written to celebrate the 350th anniversary of the journal Philosophical Transactions of the Royal Society.
凯瑟琳·朗斯代尔女爵士是英国皇家学会首批两位女性会员之一,她最初是伟大的英国科学家、诺贝尔奖获得者威廉·亨利·布拉格的学生。她最初因解决了六甲基苯的晶体结构而声名鹊起,从而证明苯环是平面的,这对有机化学非常重要,此前虽有人提出但未得到证实。当时晶体结构的解析尚处于起步阶段,在那个时代这项工作被视为一项重大成就。作为当时罕见的女性物理学家,朗斯代尔对X射线衍射的各个方面产生了兴趣,尤其发表了一篇重要论文,论述了一种使用强发散源而非通常的高度准直光束的衍射形式。由此获得的照片显示出一系列弧线和圆圈,其位置非常敏感,可用于确定钻石等晶体的质量,甚至能以极高的精度计算其晶格尺寸以及碳 - 碳键长。朗斯代尔不仅以科学家闻名,还以和平活动家以及公谊会的活跃成员而为人所知。这篇评论文章是为庆祝《皇家学会哲学学报》创刊350周年而撰写的。