铑（III）催化的芳烃肟醚导向的通过氧化C-H/C-H交叉偶联实现的杂芳基化反应。
Rh(III)-catalyzed oxime ether-directed heteroarylation of arene through oxidative C-H/C-H cross-coupling.
作者信息
Qin Dekun, Wang Jing, Qin Xurong, Wang Chunxia, Gao Ge, You Jingsong
机构信息
Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Medical School, Sichuan University, 29 Wangjiang Road, Chengdu 610064, P. R. China.
出版信息
Chem Commun (Camb). 2015 Apr 11;51(28):6190-3. doi: 10.1039/c5cc00387c.
PMID:25753941
Abstract
A rhodium(III)-catalyzed dehydrogenative cross-coupling reaction has been developed for the synthesis of bi(hetero)aryl structures by using oxime ethers as the directing group. This protocol features a relatively broad substrate scope and a good tolerance of functional groups.
摘要
已开发出一种铑（III）催化的脱氢交叉偶联反应，用于以肟醚作为导向基团合成双（杂）芳基结构。该方法具有相对广泛的底物范围和对官能团的良好耐受性。
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