源于致幻植物细叶含羞草的生物碱育亨胺的仿生全合成及结构修正
Bioinspired total synthesis and structural revision of yuremamine, an alkaloid from the entheogenic plant Mimosa tenuiflora.
作者信息
Calvert Matthew B, Sperry Jonathan
机构信息
School of Chemical Sciences, The University of Auckland, 23 Symonds Street, Auckland, 1010, New Zealand.
出版信息
Chem Commun (Camb). 2015 Apr 11;51(28):6202-5. doi: 10.1039/c5cc00380f.
PMID:25756921
Abstract
Guided by a biosynthetic hypothesis, a serendipitous total synthesis of yuremamine has resulted in its structural revision from the putative pyrroloindole (1) to the flavonoidal indole (2), which was initially proposed as a biosynthetic intermediate.
摘要
在生物合成假说的指导下，对育亨胺进行的一次意外全合成导致其结构从假定的吡咯并吲哚（1）修正为黄酮类吲哚（2），而黄酮类吲哚（2）最初被提议作为生物合成中间体。
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