Krompiec Stanisław, Filapek Michał, Grudzka-Flak Iwona, Slodek Aneta, Kula Sławomir, Malecki Jan Grzegorz, Malarz Joanna, Szafraniec-Gorol Grażyna, Penkala Mateusz, Schab-Balcerzak Ewa, Paluch Marian, Mierzwa Michał, Matussek Marek, Szlapa Agata, Pajak Michał, Blach Dariusz, Marcol Beata, Danikiewicz Witold, Boharewicz Bartosz, Iwan Agnieszka
Institute of Chemistry, Faculty of Mathematics, Physics and Chemistry, University of Silesia, Szkolna 9, Katowice 40-007, Poland.
Institute of Physics, Faculty of Mathematics, Physics and Chemistry, University of Silesia, Uniwersytecka 4, Katowice 40-007, Poland.
Molecules. 2015 Mar 12;20(3):4565-93. doi: 10.3390/molecules20034565.
New catalytically or high pressure activated reactions and routes, including coupling, double bond migration in allylic systems, and various types of cycloaddition and dihydroamination have been used for the synthesis of novel bithiophene derivatives. Thanks to the abovementioned reactions and routes combined with non-catalytic ones, new acetylene, butadiyne, isoxazole, 1,2,3-triazole, pyrrole, benzene, and fluoranthene derivatives with one, two or six bithiophenyl moieties have been obtained. Basic sources of crucial substrates which include bithiophene motif for catalytic reactions were 2,2'-bithiophene, gaseous acetylene and 1,3-butadiyne.
新的催化或高压活化反应及路线，包括偶联反应、烯丙基体系中的双键迁移以及各种环加成和二氢胺化反应，已被用于新型联噻吩衍生物的合成。由于上述反应及路线与非催化反应相结合，已获得了带有一个、两个或六个联噻吩基元的新型乙炔、丁二炔、异恶唑、1,2,3-三唑、吡咯、苯和荧蒽衍生物。催化反应关键底物的基本来源包括含有联噻吩基序的2,2'-联噻吩、气态乙炔和1,3-丁二炔。
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