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4-[(4-氨基苯基)-(4-亚氨基-1-环己-2,5-二烯基亚甲基)]苯胺盐酸盐量子效率中的溶剂依赖性

Solvent Dependency in the Quantum Efficiency of 4-[(4-Aminophenyl)-(4-imino-1-cyclohexa-2, 5- dienylidene) methyl] Aniline Hydrochloride.

作者信息

Pathrose Bini, Nampoori V P N, Radhakrishnan P, Sahira H, Mujeeb A

机构信息

International School of Photonics, Cochin University of Science and Technology, Cochin, Kerala, India,

出版信息

J Fluoresc. 2015 May;25(3):739-44. doi: 10.1007/s10895-015-1560-y. Epub 2015 Mar 29.

Abstract

In the present work dual beam thermal lens technique is used for studying the solvent dependency on the quantum efficiency of a novel dye used for biomedical applications. The role of solvent in the absolute fluorescence quantum yield of 4-[(4-Aminophenyl)-(4-imino-1-cyclohexa-2, 5- dienylidene) methyl] aniline hydrochloride is studied using thermal lens technique. It is observed that the variation in solvents and its concentration results considerable variations in the fluorescence quantum yield. These variations are due to the non-radiative relaxation of the absorbed energy and because of the different solvent properties. The highest quantum yield of the dye is observed in the polar protic solvent-water.

摘要

在本工作中,双光束热透镜技术用于研究溶剂对一种用于生物医学应用的新型染料量子效率的依赖性。使用热透镜技术研究了溶剂在4-[(4-氨基苯基)-(4-亚氨基-1-环己-2,5-二烯基亚甲基)]苯胺盐酸盐绝对荧光量子产率中的作用。观察到溶剂及其浓度的变化导致荧光量子产率有相当大的变化。这些变化是由于吸收能量的非辐射弛豫以及不同的溶剂性质。在极性质子溶剂水当中观察到该染料的最高量子产率。

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