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铝硅酸盐体系中分级结构的循环生长

Cyclic growth of hierarchical structures in the aluminum-silicate system.

作者信息

Dyonizy Agnieszka, Kaminker Vitaliy, Wieckowska Joanna, Krzywicki Tomasz, Pantaleone Jim, Nowak Piotr, Maselko Jerzy

机构信息

Department of Chemistry, Technical University, Wroclaw, Poland.

Department of Physics, University of Alaska Anchorage, Anchorage, AK USA.

出版信息

J Syst Chem. 2015;6(1):3. doi: 10.1186/s13322-015-0007-9. Epub 2015 Mar 6.

Abstract

BACKGROUND

Biological structures grow spontaneously from a seed, using materials supplied by the environment. These structures are hierarchical, with the 'building blocks' on each level constructed from those on the lower level. To understand and model the processes that occur on many levels, and later construct them, is a difficult task. However interest in this subject is growing. It is now possible to study the spontaneous growth of hierarchical structures in simple, two component chemical systems.

RESULTS

Aluminum-silicate systems have been observed to grow into structures that are approximately conical. These structures are composed of multiple smaller cones with several hierarchical levels of complexity. On the highest level the system resembles a metropolis, with a horizontal resource distribution network connecting vertical, conical structures. The cones are made from many smaller cones that are connected together forming a whole with unusual behavior. The growth is observed to switch periodically between the vertical and horizontal directions.

CONCLUSION

A structure grown in a dish is observed to have many similarities to other hierarchical systems such as biological organisms or cities. This system may provide a simple model system to search for universal laws governing the growth of complex hierarchical structures. Graphical AbstractSide view of the chemical structure made from many vertical cones to form a chemical metropolis. The tallest structure is 17 cm high.

摘要

背景

生物结构从种子开始自发生长,利用环境提供的物质。这些结构具有层次性,每一层的“构建块”由下一层的构建块构成。要理解和模拟在多个层次上发生的过程,并随后构建这些过程,是一项艰巨的任务。然而,对这一主题的兴趣正在增加。现在有可能在简单的二元化学体系中研究层次结构的自发生长。

结果

观察到铝硅酸盐体系生长成近似圆锥形的结构。这些结构由多个较小的锥体组成,具有几个层次的复杂性。在最高层次上,该体系类似于一个大都市,有一个水平的资源分布网络连接着垂直的圆锥形结构。这些锥体由许多连接在一起的较小锥体组成,形成一个具有异常行为的整体。观察到生长在垂直和水平方向之间周期性地切换。

结论

观察到在培养皿中生长的一种结构与生物有机体或城市等其他层次体系有许多相似之处。该体系可能提供一个简单的模型体系,以寻找支配复杂层次结构生长的普遍规律。图形摘要由许多垂直锥体形成化学大都市的化学结构的侧视图。最高的结构高17厘米。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b8f2/4374113/04c1477a3281/13322_2015_7_Figa_HTML.jpg

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