Sueki Shunsuke, Kuninobu Yoichiro
Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Chem Commun (Camb). 2015 May 4;51(36):7685-8. doi: 10.1039/c5cc01569c.
We successfully developed rhodium-catalysed synthesis of multi-substituted silylindenes from 2 equivalents of aryl alkynes and 1 equivalent of hydrosilanes in moderate to good yields via C-H bond activation for the first time. The silyl groups of the obtained silylindenes could be converted to several other functional groups.
我们首次通过C-H键活化，以中等至良好的产率成功开发了铑催化的由2当量芳基炔烃和1当量硅烷合成多取代甲硅烷基茚的方法。所得甲硅烷基茚的甲硅烷基可转化为其他几个官能团。
