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水触发自组装缩聚反应用于从氨基酸酯一锅法合成环矩阵聚磷腈纳米颗粒。

Water-triggered self-assembly polycondensation for the one-pot synthesis of cyclomatrix polyphosphazene nanoparticles from amino acid ester.

作者信息

Huang Zhangjun, Chen Shuangshuang, Lu Xuemin, Lu Qinghua

机构信息

School of Chemistry and Chemical Engineering, the State Key Laboratory of Metal Matrix Composites, Shanghai Jiaotong University, Shanghai 200240, P. R. China.

出版信息

Chem Commun (Camb). 2015 May 14;51(39):8373-6. doi: 10.1039/c5cc00735f.

DOI:10.1039/c5cc00735f
PMID:25891751
Abstract

Water-triggered self-assembly polycondensation was proposed for preparation of cyclomatrix polyphosphazene nanoparticles from amino acid esters, and a critical solubility parameter was found to determine whether the nanoparticles were formed. Based on this rule, we also investigated the control of the size of its nanoparticles.

摘要

提出了水引发自组装缩聚法，用于由氨基酸酯制备环矩阵聚磷腈纳米颗粒，并发现了一个关键的溶解度参数来确定是否形成纳米颗粒。基于此规则，我们还研究了对其纳米颗粒尺寸的控制。

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