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Contribution to the benchmark for ternary mixtures: Measurement of diffusion and Soret coefficients of ternary system tetrahydronaphtalene-isobutylbenzene-n-dodecane with mass fractions 80-10-10 at 25 °C.

作者信息

Galand Quentin, Van Vaerenbergh Stéfan

机构信息

Microgravity Research Center, Université libre de Bruxelles, Dept. Chemical Physics, Avenue F. D. Roosevelt, B-1050, Brussels, Belgium,

出版信息

Eur Phys J E Soft Matter. 2015 Apr;38(4):26. doi: 10.1140/epje/i2015-15026-3. Epub 2015 Apr 27.

DOI:10.1140/epje/i2015-15026-3
PMID:25916231
Abstract

This paper provides the molecular diffusion and Soret coefficients of the ternary system 1,2,3,4-tetrahydronaphtalene, isobutylbenzene, n -dodecane system at mass fractions 0.8-0.1-0.1 and temperature 25 (°)C for implementation into the benchmark presented in this topical issue. The Soret coefficients are determined by digital interferometry using the data of DSC-DCMIX microgravity experiment. The method used takes into account the influence of the thermal field on the Soret separations and the selection of the image processing techniques results in reproducible Soret coefficients.The diffusion coefficients are obtained by the Open Ended Capillary technique The fitting of the data collected through a set of two complementary experimental runs allows retrieving the four Fickian diffusion coefficients.

摘要

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本文引用的文献

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Benchmark values for the Soret, thermodiffusion and molecular diffusion coefficients of the ternary mixture tetralin+isobutylbenzene+n-dodecane with 0.8-0.1-0.1 mass fraction.质量分数为0.8-0.1-0.1的三元混合物四氢萘+异丁基苯+正十二烷的索雷特系数、热扩散系数和分子扩散系数的基准值。
Eur Phys J E Soft Matter. 2015 Apr;38(4):30. doi: 10.1140/epje/i2015-15030-7. Epub 2015 Apr 28.
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