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对三元混合物基准的贡献:在国际空间站上测量1,2,3,4-四氢萘、异丁基苯和十二烷中的扩散系数和索雷特系数

Contribution to the benchmark for ternary mixtures: Measurement of diffusion and Soret coefficients in 1,2,3,4-tetrahydronaphthalene, isobutylbenzene, and dodecane onboard the ISS.

作者信息

Khlybov Oleg A, Ryzhkov Ilya I, Lyubimova Tatyana P

机构信息

Institute of Continuous Media Mechanics, UB RAS, Koroleva St. 1, 614013, Perm, Russia.

出版信息

Eur Phys J E Soft Matter. 2015 Apr;38(4):29. doi: 10.1140/epje/i2015-15029-0. Epub 2015 Apr 28.

DOI:10.1140/epje/i2015-15029-0
PMID:25916235
Abstract

The paper is devoted to processing the data of DCMIX 1 space experiment. In this experiment, the Optical digital interferometry was used to measure the diffusion and Soret coefficients in the ternary mixture of 1,2,3,4-tetrahydronaphthalene, isobutylbenzene and n-dodecane at mass fractions of 0.8/0.1/0.1 and at 25°C. The raw interferometric images were processed to obtain the temporal and spatial evolution of refractive indices for two laser beams of different wavelengths. The method for extracting the diffusion and thermal diffusion coefficients originally developed for optical beam deflection was extended to optical digital interferometry allowing for the spatial variation of refractive index along the diffusion path. The method was validated and applied to processing the data for Soret and diffusion steps in 5 experimental runs. The obtained results for the Soret coefficients and one of the eigenvalues of diffusion matrix showed acceptable agreement within each step. The second eigenvalue was not determined with sufficient accuracy.

摘要

本文致力于处理DCMIX 1空间实验的数据。在该实验中,采用光学数字干涉测量法测量了质量分数为0.8/0.1/0.1的1,2,3,4-四氢萘、异丁基苯和正十二烷三元混合物在25°C时的扩散系数和索雷特系数。对原始干涉图像进行处理,以获得不同波长的两束激光的折射率的时间和空间演变。最初为光束偏转开发的提取扩散系数和热扩散系数的方法被扩展到光学数字干涉测量法,该方法考虑了沿扩散路径折射率的空间变化。该方法经过验证,并应用于处理5次实验运行中索雷特和扩散步骤的数据。在每个步骤中,获得的索雷特系数和扩散矩阵的一个特征值的结果显示出可接受的一致性。第二个特征值的确定精度不够。

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本文引用的文献

1
Measurement of the Soret and diffusion coefficients for benchmark binary mixtures by means of digital interferometry.利用数字干涉法测量基准二元混合物的索雷特(Soret)系数和扩散系数。
J Chem Phys. 2011 Jan 28;134(4):044524. doi: 10.1063/1.3546036.
2
Measurement of diffusion and thermal diffusion in ternary fluid mixtures using a two-color optical beam deflection technique.采用双色光偏转技术测量三元流体混合物中的扩散和热扩散。
J Chem Phys. 2010 May 7;132(17):174506. doi: 10.1063/1.3421547.
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On measurement of molecular and thermal diffusion coefficients in multicomponent mixtures.
Eur Phys J E Soft Matter. 2019 Mar 7;42(3):27. doi: 10.1140/epje/i2019-11789-7.
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Thermodiffusion in multicomponent -alkane mixtures.多组分烷烃混合物中的热扩散
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Stationary and transient Soret separation in a binary mixture with a consolute critical point.
Eur Phys J E Soft Matter. 2016 Dec;39(12):130. doi: 10.1140/epje/i2016-16130-6. Epub 2016 Dec 23.
6
Editorial: Thermal non-equilibrium phenomena in multi-component fluids.社论:多组分流体中的热非平衡现象
Eur Phys J E Soft Matter. 2015 Apr;38(4):31. doi: 10.1140/epje/i2015-15031-6. Epub 2015 Apr 29.
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