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商业海鲜中有毒和必需金属的测定:利用电感耦合等离子体质谱法检测紫海胆

Toxic and essential metals determination in commercial seafood: Paracentrotus lividus by ICP-MS.

作者信息

Salvo Andrea, Cicero Nicola, Vadalà Rossella, Mottese Antonio Francesco, Bua Daniel, Mallamace Domenico, Giannetto Carlo, Dugo Giacomo

机构信息

a Dipartimento di Scienze dell'Ambiente , della Sicurezza, del Territorio, degli Alimenti e della Salute "Carmelo Abbate"Università di Messina , V.le F. Stagno d'Alcontres 31, 98166 - Messina , Italy.

b Dipartimento di Scienze Economiche , Aziendali, Ambientali e Metodologie Quantitative, Università di Messina , Piazza Pugliatti 1, 98122 - Messina , Italy.

出版信息

Nat Prod Res. 2016;30(6):657-64. doi: 10.1080/14786419.2015.1038261. Epub 2015 Apr 28.

Abstract

Toxic and essential metals content was determined by inductively coupled plasma mass spectrometry in commercial sea urchins samples from the Mediterranean Sea and Pacific Ocean. Results show that Chilean samples have the highest values of Cd, As, Ni, Cr and V; Spanish samples have the maximum Hg content while Sicilian samples have the lowest content of toxic metals. The toxic metal traces were compared with the limits of European Community (EC) No. 1881/2006 for bivalve molluscs. All samples exceed Pb and Cd limit levels; regarding Hg levels, only Sicilian and Sardinian samples have Hg content below the EC limits. The dietary intake of toxic and essential elements was evaluated for an adult. Furthermore, our study highlights a correlation between the toxic elements content and the marine environmental conditions of the places of origin even though only the generic FAO fishing area is specified.

摘要

采用电感耦合等离子体质谱法测定了来自地中海和太平洋的商业海胆样本中的有毒金属和必需金属含量。结果表明,智利样本中的镉、砷、镍、铬和钒含量最高;西班牙样本中的汞含量最高,而西西里岛样本中的有毒金属含量最低。将有毒金属痕量与欧盟第1881/2006号法规对双壳贝类的限量进行了比较。所有样本均超过了铅和镉的限量水平;关于汞含量,只有西西里岛和撒丁岛的样本汞含量低于欧盟限量。评估了一名成年人对有毒和必需元素的膳食摄入量。此外,我们的研究强调了有毒元素含量与产地海洋环境条件之间的相关性,尽管仅指定了粮农组织的一般渔区。

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