Zhou Xiangping, Ji Jian, Wang Di, Duan Xuezhi, Qian Gang, Chen De, Zhou Xinggui
State Key Laboratory of Chemical Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China.
Chem Commun (Camb). 2015 May 25;51(42):8853-6. doi: 10.1039/c5cc00786k.
Hierarchical structured α-Al2O3 is shown to be able to effectively disperse and immobilize iron species, in comparison with commercial α-Al2O3. After promotion using an appropriate amount of sulfur, iron catalysts exhibit not only enhanced Fischer-Tropsch synthesis activity and selectivity toward lower olefins, but also increased resistance against carbon deposits.
与商业α-Al2O3相比,分级结构的α-Al2O3能够有效地分散和固定铁物种。在使用适量硫进行促进后,铁催化剂不仅表现出增强的费托合成活性和对低级烯烃的选择性,而且还提高了抗积碳性能。