†MOE Key Laboratory of Analysis Detection Technology for Food Safety, Fujian Provincial Key Laboratory of Analysis and Detection for Food Safety, and College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China.
‡Key Laboratory of Medicinal Chemistry for Natural Resource (Yunnan University), Ministry of Education, School of Chemical Science and Technology, Yunnan University, Kunming, Yunnan 650091, China.
ACS Appl Mater Interfaces. 2015 Jun 3;7(21):11322-9. doi: 10.1021/acsami.5b01706. Epub 2015 May 18.
Novel metal-organic frameworks (MOFs) based solid catalysts have been synthesized by encapsulating Hemin into the HKUST-1 MOF materials. These have been first applied in the chemiluminescence field with outstanding performance. The functionalized MOFs not only maintain an excellent catalytic activity inheriting from Hemin but also can be cyclically utilized as solid mimic peroxidases in the neutral condition. The synthesized Hemin@HKUST-1 composites have been used to develop practical sensors for H2O2 and glucose with wide response ranges and low detection limits. It was envisioned that catalyst-functionalized MOFs for chemiluminescence sensing would have promising applications in green, selective, and sensitive detection of target analytes in the future.
新型金属-有机骨架（MOFs）基固体催化剂已通过将血红素封装到 HKUST-1 MOF 材料中合成。这些材料首次在化学发光领域得到应用，表现出优异的性能。功能化的 MOFs 不仅保持了血红素所具有的优异的催化活性，而且还可以在中性条件下作为固体模拟过氧化物酶循环使用。合成的血红素@HKUST-1 复合材料已被用于开发用于 H2O2 和葡萄糖的实用传感器，具有较宽的响应范围和较低的检测限。可以预见，用于化学发光传感的催化剂功能化 MOFs 在未来对目标分析物的绿色、选择性和灵敏检测中具有广阔的应用前景。
