Jo Min Sung, Seo Hyo Won, Tawfik Wael Z, Yang Seung Bea, Lee Jung Ju, Ryu Sang Wan, Ha Jun Seok, Jeon Seong Ran, Cui Hao, Park Si Hyun, Lee June Key
J Nanosci Nanotechnol. 2014 Aug;14(8):6108-11. doi: 10.1166/jnn.2014.8295.
380 nm Ultraviolet (UV) light emitting diodes (LEDs) were grown on patterned n-type GaN substrate (PNS). Wet etched self-assembled indium tin oxide (ITO) nano clusters serves as dry etching mask for converting the SiO2 layer grown on n-GaN template into SiO2 nano dots by inductively coupled plasma etching. In the pre-experiment, crystal quality and optical properties of n-GaN were greatly improved by applying PNS process. In this work, etch-pits density (EPD) method confirmed that PNS with SiO2 nano dots have superior crystalline properties. Thus Reference LED without PNS, 1-step PNS LEDs with SiO2 nano dots size were 200 nm, 250 nm, 300 nm and 300 nm 2-step PNS LED were fabricated. LEDs show almost the same operating voltage of about 3.4 V at an injection current of 50 mA. Light intensity was enhanced by ~2.1 times and 3.2 times for 300 nm 1-step and 300 nm 2-step PNS, respectively. FDTD simulation results show a similar tendency. As a result, PNS promotes epitaxial lateral overgrowth (ELOG) for defect reduction as well as act as a light scattering point.
380纳米紫外(UV)发光二极管(LED)生长在图案化的n型氮化镓衬底(PNS)上。湿法蚀刻的自组装铟锡氧化物(ITO)纳米团簇用作干法蚀刻掩膜,通过电感耦合等离子体蚀刻将生长在n型氮化镓模板上的二氧化硅层转换为二氧化硅纳米点。在预实验中,通过应用PNS工艺,n型氮化镓的晶体质量和光学性能得到了极大改善。在这项工作中,蚀刻坑密度(EPD)方法证实,带有二氧化硅纳米点的PNS具有优异的晶体性能。因此,制备了无PNS的参考LED、二氧化硅纳米点尺寸为200纳米、250纳米、300纳米的一步PNS LED以及300纳米的两步PNS LED。在50毫安的注入电流下,LED的工作电压几乎相同,约为3.4伏。对于300纳米的一步PNS和300纳米的两步PNS,光强分别提高了约2.1倍和3.2倍。时域有限差分(FDTD)模拟结果显示出类似的趋势。结果表明,PNS促进外延横向过生长(ELOG)以减少缺陷,同时还充当光散射点。