亚砜作为高效配体在过渡金属催化中的出现。

The emergence of sulfoxides as efficient ligands in transition metal catalysis.

机构信息

School of Chemistry and Biochemistry, University of Western Australia, 35 Stirling Highway, 6009, Crawley, Australia.

出版信息

Chem Soc Rev. 2015 Jun 7;44(11):3834-60. doi: 10.1039/c4cs00524d.

Abstract

Sulfoxides are capable of forming stable complexes with transition metals and there have been many comprehensive studies into their binding properties. However, the use of sulfoxides, particularly chiral sulfoxides, as ligands in transition metal catalysis is rather less well developed. This review aims to describe these catalytic studies and covers new developments that are showing very promising results and that have led to a renewed interest in this field.

摘要

亚砜能够与过渡金属形成稳定的配合物，并且已经有许多关于它们的配位性质的综合研究。然而，亚砜（特别是手性亚砜）作为过渡金属催化剂中的配体的应用还不太发达。本综述旨在描述这些催化研究，并涵盖了新的发展，这些发展显示出非常有前途的结果，并重新引起了人们对这一领域的兴趣。