Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu, 610041, China.
College of Chemical Engineering, Sichuan University, Chengdu, 610065, China.
Top Curr Chem (Cham). 2019 Feb 12;377(2):8. doi: 10.1007/s41061-019-0232-9.
Since the original idea was explored by James in 1976, the use of chiral sulfoxides as ligands with transition metals in asymmetric catalysis has undergone a long period of development. There have been many studies into their properties, design and application in various kinds of asymmetric transformations. In this article, we document the literatures on chiral sulfoxide ligands in asymmetric catalytic reactions.
自 1976 年 James 首次提出这一设想以来,手性亚砜作为与过渡金属配位的配体在不对称催化中得到了长足的发展。人们对手性亚砜的性质、设计及其在各种不对称转化中的应用进行了大量的研究。本文综述了手性亚砜配体在不对称催化反应中的应用文献。