钴(III)催化的异氰酸酯和酰基叠氮与芳基和烯基 C-H 的氨甲酰化反应。
Cobalt(III)-Catalyzed Aryl and Alkenyl C-H Aminocarbonylation with Isocyanates and Acyl Azides.
机构信息
Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstraße 2, 37077 Göttingen (Germany) http://www.ackermann.chemie.uni-goettingen.de/
Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstraße 2, 37077 Göttingen (Germany) http://www.ackermann.chemie.uni-goettingen.de/.
出版信息
Angew Chem Int Ed Engl. 2015 Jul 13;54(29):8551-4. doi: 10.1002/anie.201501926. Epub 2015 May 12.
Expedient C-H aminocarbonylations of unactivated (hetero)arenes and alkenes were accomplished with a cobalt(III) catalyst that shows high functional group tolerance. The C-H functionalization occurred with excellent chemo-, site-, and diastereoselectivity and enabled step-economical reactions with isocyanates or acyl azides.
一种钴(III)催化剂能够实现未活化（杂）芳环和烯烃的高官能团耐受性的 C-H 氨甲酰化反应。该 C-H 官能团化反应具有优异的化学选择性、位置选择性和非对映选择性，并能与异氰酸酯或酰基叠氮化物进行经济有效的反应。
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