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一种醇铟配合物对环状酯开环聚合的高活性。

High activity of an indium alkoxide complex toward ring opening polymerization of cyclic esters.

作者信息

Quan Stephanie M, Diaconescu Paula L

机构信息

Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095, USA.

出版信息

Chem Commun (Camb). 2015 Jun 14;51(47):9643-6. doi: 10.1039/c5cc01312g.

DOI:10.1039/c5cc01312g
PMID:25973852
Abstract

An indium complex supported by a ferrocene-derived Schiff base ligand has an unprecedented high activity toward ε-caprolactone, δ-valerolactone, and β-butyrolactone. l-Lactide, d,l-lactide, and trimethylene carbonate polymerizations also showed moderate to high activity.

摘要

一种由二茂铁衍生的席夫碱配体支撑的铟配合物对ε-己内酯、δ-戊内酯和β-丁内酯具有前所未有的高活性。左旋丙交酯、外消旋丙交酯和碳酸三亚甲酯的聚合反应也显示出中等到高的活性。

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