Vazquez-Lima Hugo, Norheim Hans-Kristian, Einrem Rune F, Ghosh Abhik
Department of Chemistry and Center for Theoretical and Computational Chemistry, UiT - The Arctic University of Norway, 9037 Tromsø, Norway.
Dalton Trans. 2015 Jun 14;44(22):10146-51. doi: 10.1039/c5dt01495f.
Multiple lines of evidence, including electronic absorption spectroscopy, infrared spectroscopy, and broken-symmetry DFT calculations, indicate that the well-known FeNO corroles, long assumed to be {FeNO}(6) complexes, are in fact better described as {FeNO}(7)-(corrole˙(2-)).
包括电子吸收光谱、红外光谱和破缺对称性密度泛函理论计算在内的多条证据表明，长期以来被认为是{FeNO}(6)配合物的著名FeNO 卟吩类化合物，实际上更宜描述为{FeNO}(7)-(卟吩二价阴离子自由基)。
