金属有机框架的“点击”后功能化用于设计活性单中心多相钌（III）催化剂。
"Click" post-functionalization of a metal-organic framework for engineering active single-site heterogeneous Ru(iii) catalysts.
作者信息
Wu Suntao, Chen Liyu, Yin Biaolin, Li Yingwei
机构信息
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China.
出版信息
Chem Commun (Camb). 2015 Jun 18;51(48):9884-7. doi: 10.1039/c5cc02741a.
PMID:25995141
Abstract
We present a general strategy for incorporating π-conjugated NNN-chelators (e.g., terpyridyl moiety) into a porous metal-organic framework (MOF) MIL-101(Cr) by using the "click" post-functionalization. The functionalized MOF could be used as a platform for metalation to yield highly active and stable single-site heterogeneous metal (e.g., Ru(iii)) catalysts.
摘要
我们提出了一种通用策略，即通过“点击”后功能化将π共轭NNN螯合剂（例如，三联吡啶部分）引入多孔金属有机框架（MOF）MIL-101（Cr）中。功能化的MOF可用作金属化平台，以制备高活性和稳定的单中心多相金属（例如，Ru(iii)）催化剂。
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