钌催化酸酐与炔烃的脱羰加成反应：异香豆素和α-吡喃酮的简便合成
Ruthenium-catalyzed decarbonylative addition reaction of anhydrides with alkynes: a facile synthesis of isocoumarins and α-pyrones.
作者信息
Prakash Rashmi, Shekarrao Kommuri, Gogoi Sanjib, Boruah Romesh C
机构信息
Medicinal Chemistry Division, CSIR-North East Institute of Science and Technology, Jorhat 785006, India.
出版信息
Chem Commun (Camb). 2015 Jun 21;51(49):9972-4. doi: 10.1039/c5cc03311j.
PMID:25997656
Abstract
A novel ruthenium catalyzed straightforward and efficient synthesis of isocoumarin and α-pyrone derivatives has been accomplished by the decarbonylative addition reaction of anhydrides with alkynes under thermal conditions.
摘要
通过酸酐与炔烃在热条件下的脱羰基加成反应，实现了一种新颖的钌催化直接且高效地合成异香豆素和α-吡喃酮衍生物的方法。
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