Faculty of Pharmacy, University of Ljubljana, Aškerčeva 7, SI-1000 Ljubljana, Slovenia.
Faculty of Pharmacy, University of Ljubljana, Aškerčeva 7, SI-1000 Ljubljana, Slovenia.
Food Chem. 2008 Jul 15;109(2):293-8. doi: 10.1016/j.foodchem.2007.12.032. Epub 2008 Feb 5.
Salicylaldehyde (2-hydroxybenzaldehyde) was identified as a characteristic component of buckwheat groats aroma by a sensory analysis guided fractionation of the extract. The extract with the strongest odour was prepared by petroleum ether extraction of water soaked groats. This extract was further extracted with sodium hydrogen carbonate solution and purified by a preparative layer chromatography and identified by NMR, MS and IR spectroscopy. A capillary electrophoresis method was developed and used to determine salicylaldehyde content in buckwheat groats and flour samples. Traditionally dehulled buckwheat grain, which had the strongest odour, contained the highest concentration (1.6ppm) of salicylaldehyde with an odour activity value (OAV) of 216.
水杨醛(2-羟基苯甲醛)被鉴定为荞麦粒香气的特征成分,通过对提取物进行感官分析导向的分段来确定。通过水浸泡的荞麦粒的石油醚萃取制备了具有最强气味的提取物。该提取物用碳酸氢钠溶液进一步提取,然后通过制备层色谱法纯化,并通过 NMR、MS 和 IR 光谱鉴定。开发了毛细管电泳法,并用于测定荞麦粒和面粉样品中的水杨醛含量。传统去壳的荞麦粒具有最强的气味,其水杨醛含量最高(1.6ppm),气味活度值(OAV)为 216。