一种用于高效二氧化碳吸附的基于三嗪的共价有机聚合物。
A triazine-based covalent organic polymer for efficient CO2 adsorption.
作者信息
Gomes Ruth, Bhanja Piyali, Bhaumik Asim
机构信息
Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur 700 032, India.
出版信息
Chem Commun (Camb). 2015 Jun 21;51(49):10050-3. doi: 10.1039/c5cc02147b.
A new triazine functionalized hexagonally ordered covalent organic polymer (TRITER-1) has been synthesized via the Schiff-base condensation reaction between a tailor made triamine 1,3,5-tris-(4-aminophenyl)triazine (TAPT) and terephthaldehyde. This ordered porous polymer showed a high BET surface area (716 m(2) g(-1)) and an excellent CO2 uptake capacity of 58.9 wt% at 273 K under 5 bar pressure.
一种新型的三嗪官能化六方有序共价有机聚合物（TRITER-1）已通过定制的三胺1,3,5-三（4-氨基苯基）三嗪（TAPT）与对苯二甲醛之间的席夫碱缩合反应合成。这种有序多孔聚合物具有较高的BET表面积（716 m² g⁻¹），并且在273 K、5 bar压力下具有58.9 wt%的优异二氧化碳吸附容量。
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