Vamvakeros A, Jacques S D M, Middelkoop V, Di Michiel M, Egan C K, Ismagilov I Z, Vaughan G B M, Gallucci F, van Sint Annaland M, Shearing P R, Cernik R J, Beale A M
Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ, UK.
Chem Commun (Camb). 2015 Aug 18;51(64):12752-5. doi: 10.1039/c5cc03208c.
We report the results from an operando XRD-CT study of a working catalytic membrane reactor for the oxidative coupling of methane. These results reveal the importance of the evolving solid state chemistry during catalytic reaction, particularly the chemical interaction between the catalyst and the oxygen transport membrane.
我们报告了对用于甲烷氧化偶联的工作催化膜反应器进行的原位XRD-CT研究结果。这些结果揭示了催化反应过程中不断演变的固态化学的重要性,特别是催化剂与氧传输膜之间的化学相互作用。