Oxidative Coupling of Methane: A Review Study on the Catalytic Performance.

Extensive data on the characteristics and performance of the catalysts synthesized and tested for methane oxidative coupling (OCM) is available in thousands of reports published during the last four decades. Revisiting and analyzing the general trends recognizable in those data could improve the current understanding of the catalyst functionality under different reaction conditions. This is instrumental in determining the direction of future research aiming for more efficient OCM catalysts and reactors. These are the subjects of the comprehensive analysis reported in this paper, which covers the main aspects associated with the analysis of the OCM catalytic performance, including the catalyst characteristics, reaction mechanism, and reactor operation. Special attention was devoted to analyzing these aspects in the framework of thermal-reaction engineering and, accordingly, critically reviewing the reported catalytic performances in the literature.