二芳基硒催化的烯烃邻位三氟甲硫基化反应
Diaryl Selenide Catalyzed Vicinal Trifluoromethylthioamination of Alkenes.
作者信息
Luo Jie, Zhu Zechen, Liu Yannan, Zhao Xiaodan
出版信息
Org Lett. 2015 Jul 17;17(14):3620-3. doi: 10.1021/acs.orglett.5b01727. Epub 2015 Jul 9.
PMID:26158564
Abstract
An efficient approach to vicinal trifluoromethylthioamination of alkenes with a broad substrate scope catalyzed by electron-rich diaryl selenide has been developed. This intermolecular amination strategy was successfully applied to SCF3-esterification of alkenes using weak acids as nucleophiles.
摘要
已开发出一种有效的方法，用于在富电子二芳基硒化物催化下对烯烃进行邻位三氟甲硫基胺化反应，该方法具有广泛的底物范围。这种分子间胺化策略已成功应用于以弱酸为亲核试剂的烯烃的SCF₃酯化反应。
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