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用于使金属玻璃延性化的快速焦耳加热

Flash Joule heating for ductilization of metallic glasses.

作者信息

Okulov I V, Soldatov I V, Sarmanova M F, Kaban I, Gemming T, Edström K, Eckert J

机构信息

IFW Dresden, Helmholtzstrasse 20, 01069 Dresden, Germany.

TU Dresden, Institut für Werkstoffwissenschaft, 01062 Dresden, Germany.

出版信息

Nat Commun. 2015 Jul 29;6:7932. doi: 10.1038/ncomms8932.

DOI:10.1038/ncomms8932
PMID:26219864
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4532880/
Abstract

Metallic glasses (MGs) inherit their amorphous structure from the liquid state, which predetermines their ability to withstand high loads approaching the theoretical limit. However, the absence of slip systems makes them very sensitive to the type of loading and extremely brittle in tension. The latter can be improved by precipitation of ductile crystals, which suppress a catastrophic propagation of shear bands in a glassy matrix. Here we report a novel approach to obtain MG-matrix composites with tensile ductility by flash Joule heating applied to Cu47.5Zr47.5Al5 (at.%) metallic glass. This homogeneous, volumetric and controllable rapid heat treatment allows achieving uniformly distributed metastable B2 CuZr crystals in the glassy matrix. It results in a significant tensile strain of 6.8±0.5%. Moreover, optimized adjustment of the heat-treatment conditions enables tuning of microstructure to achieve desired mechanical properties.

摘要

金属玻璃(MGs)从液态继承了其非晶态结构,这决定了它们承受接近理论极限的高负荷的能力。然而,由于缺乏滑移系,它们对加载类型非常敏感,并且在拉伸时极其脆。后者可以通过析出韧性晶体来改善,这会抑制剪切带在玻璃基体中的灾难性扩展。在此,我们报道了一种通过对Cu47.5Zr47.5Al5(原子百分比)金属玻璃施加快速焦耳加热来获得具有拉伸延展性的MG基复合材料的新方法。这种均匀、体相且可控的快速热处理能够在玻璃基体中实现均匀分布的亚稳B2 CuZr晶体。这导致了6.8±0.5%的显著拉伸应变。此外,对热处理条件的优化调整能够调节微观结构以实现所需的机械性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c0a/4532880/72703bd1f6ff/ncomms8932-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c0a/4532880/c2d8ba193913/ncomms8932-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c0a/4532880/a6cc39c006ed/ncomms8932-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c0a/4532880/193574514646/ncomms8932-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c0a/4532880/6de025cf954b/ncomms8932-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c0a/4532880/72703bd1f6ff/ncomms8932-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c0a/4532880/c2d8ba193913/ncomms8932-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c0a/4532880/a6cc39c006ed/ncomms8932-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c0a/4532880/193574514646/ncomms8932-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c0a/4532880/6de025cf954b/ncomms8932-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c0a/4532880/72703bd1f6ff/ncomms8932-f5.jpg

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1
Beating crystallization in glass-forming metals by millisecond heating and processing.通过毫秒级加热和处理在玻璃形成金属中克服结晶。
Science. 2011 May 13;332(6031):828-33. doi: 10.1126/science.1201362.
2
A damage-tolerant glass.一种耐损伤玻璃。
Nat Mater. 2011 Feb;10(2):123-8. doi: 10.1038/nmat2930. Epub 2011 Jan 9.
3
Materials science. Shape memory bulk metallic glass composites.材料科学。形状记忆块体金属玻璃复合材料。
Nat Commun. 2022 Oct 12;13(1):6017. doi: 10.1038/s41467-022-33546-9.
4
Structure-dynamics relationships in cryogenically deformed bulk metallic glass.深冷变形块状金属玻璃中的结构-动力学关系
Nat Commun. 2022 Jan 10;13(1):127. doi: 10.1038/s41467-021-27661-2.
5
In situ correlation between metastable phase-transformation mechanism and kinetics in a metallic glass.金属玻璃中亚稳相变机制与动力学的原位关联
Nat Commun. 2021 May 14;12(1):2839. doi: 10.1038/s41467-021-23028-9.
6
Fabrication of Metastable Crystalline Nanocomposites by Flash Annealing of CuZrAl Metallic Glass Using Joule Heating.通过焦耳热对CuZrAl金属玻璃进行快速退火制备亚稳结晶纳米复合材料
Nanomaterials (Basel). 2020 Jan 1;10(1):84. doi: 10.3390/nano10010084.
7
Polymorphic Transformation and Magnetic Properties of Rapidly Solidified FeCoNiSiB High-Entropy Alloys.快速凝固FeCoNiSiB高熵合金的多晶型转变及磁性能
Materials (Basel). 2019 Feb 15;12(4):590. doi: 10.3390/ma12040590.
8
Local melting to design strong and plastically deformable bulk metallic glass composites.局部熔化设计强韧可塑的大块金属玻璃复合材料。
Sci Rep. 2017 Feb 13;7:42518. doi: 10.1038/srep42518.
9
Dealloying-based interpenetrating-phase nanocomposites matching the elastic behavior of human bone.基于脱合金的互穿相纳米复合材料与人骨弹性行为相匹配。
Sci Rep. 2017 Feb 2;7(1):20. doi: 10.1038/s41598-017-00048-4.
Science. 2010 Sep 10;329(5997):1294-5. doi: 10.1126/science.1193522.
4
Development of tough, low-density titanium-based bulk metallic glass matrix composites with tensile ductility.具有拉伸延展性的坚韧、低密度钛基块状金属玻璃基复合材料的开发。
Proc Natl Acad Sci U S A. 2008 Dec 23;105(51):20136-40. doi: 10.1073/pnas.0809000106. Epub 2008 Dec 11.
5
Designing metallic glass matrix composites with high toughness and tensile ductility.设计具有高韧性和拉伸延展性的金属玻璃基复合材料。
Nature. 2008 Feb 28;451(7182):1085-9. doi: 10.1038/nature06598.
6
Microstructure controlled shear band pattern formation and enhanced plasticity of bulk metallic glasses containing in situ formed ductile phase dendrite dispersions.微观结构控制的剪切带图案形成及含原位形成的韧性相枝晶分散体的块状金属玻璃的塑性增强
Phys Rev Lett. 2000 Mar 27;84(13):2901-4. doi: 10.1103/PhysRevLett.84.2901.