Capaccioli S, Paluch M, Prevosto D, Wang Li-Min, Ngai K L
§Institute of Physics, University of Silesia, Uniwersytecka 4, 40-007 Katowice, Poland.
∥State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao, Hebei 066004, China.
J Phys Chem Lett. 2012 Mar 15;3(6):735-43. doi: 10.1021/jz201634p. Epub 2012 Feb 29.
Most glass-forming systems are composed of basic units interacting with each other with a nontrivial anharmonic potential. Naturally, relaxation and diffusion in glass formers is a many-body problem. Results from recent experimental studies are presented to show the effects of many-body relaxation and diffusion manifested on the dynamic properties of glass formers. Considering that the effects are general and critical, the problem of glass transition will not be solved until the many-body nature of the relaxation process has been incorporated fundamentally into any theory.
大多数玻璃形成系统由基本单元组成,这些基本单元通过非平凡的非谐势相互作用。自然地,玻璃形成体中的弛豫和扩散是一个多体问题。本文展示了近期实验研究的结果,以说明多体弛豫和扩散对玻璃形成体动力学性质的影响。鉴于这些影响具有普遍性和关键性,在弛豫过程的多体性质从根本上被纳入任何理论之前,玻璃转变问题都无法得到解决。