RIKEN Center for Emergent Matter Science (CEMS), 2-1 Hirosawa, Wako, Saitama, 351-0198, Japan.
Department of Applied Chemistry, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan.
Adv Mater. 2015 Oct 21;27(39):6014-20. doi: 10.1002/adma.201502339. Epub 2015 Aug 27.
Slab optical waveguide absorption spectra reveal that surface segregated monolayers of a vertically oriented poly(3-buthylthiophene) derivative have large optical anisotropy, and that confinement of the polymer chains in the isolated monolayer causes strong H-aggregation.
平板光波导吸收谱表明,垂直取向的聚(3-丁基噻吩)衍生物的表面分离单层具有较大的光学各向异性,并且聚合物链在隔离的单层中的受限导致强 H-聚集。