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聚(3-烷基噻吩)在表面单层中的光学各向异性和强 H 聚集。

Optical anisotropy and strong H-aggregation of poly(3-alkylthiophene) in a surface monolayer.

机构信息

RIKEN Center for Emergent Matter Science (CEMS), 2-1 Hirosawa, Wako, Saitama, 351-0198, Japan.

Department of Applied Chemistry, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan.

出版信息

Adv Mater. 2015 Oct 21;27(39):6014-20. doi: 10.1002/adma.201502339. Epub 2015 Aug 27.

DOI:10.1002/adma.201502339
PMID:26310575
Abstract

Slab optical waveguide absorption spectra reveal that surface segregated monolayers of a vertically oriented poly(3-buthylthiophene) derivative have large optical anisotropy, and that confinement of the polymer chains in the isolated monolayer causes strong H-aggregation.

摘要

平板光波导吸收谱表明,垂直取向的聚(3-丁基噻吩)衍生物的表面分离单层具有较大的光学各向异性,并且聚合物链在隔离的单层中的受限导致强 H-聚集。

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