通过配位导向自组装将一种简单的苯并噻二唑稠合四硫富瓦烯组装成低带隙金属凝胶。
Coordination-directed self-assembly of a simple benzothiadiazole-fused tetrathiafulvalene to low-bandgap metallogels.
作者信息
Amacher Anneliese M, Puigmartí-Luis Josep, Geng Yan, Lebedev Victor, Laukhin Vladimir, Krämer Karl, Hauser Jürg, Amabilino David B, Decurtins Silvio, Liu Shi-Xia
机构信息
Departement für Chemie und Biochemie, Universität Bern, Freiestrasse 3, CH-3012 Bern, Switzerland.
出版信息
Chem Commun (Camb). 2015 Oct 18;51(81):15063-6. doi: 10.1039/c5cc06819c.
Coordination-driven gelation of a benzothiadiazole-fused tetrathiafulvalene (TTF) is demonstrated. This is the first work reporting highly stable metallogels based on a donor-acceptor conjugate with such a simple structure for the construction of new low-bandgap materials with various functional properties and novel nanostructures.
已证实苯并噻二唑稠合四硫富瓦烯（TTF）的配位驱动凝胶化。这是第一项报道基于具有如此简单结构的供体-受体共轭物的高度稳定金属凝胶的工作，用于构建具有各种功能特性和新型纳米结构的新型低带隙材料。
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