Li Fuping, Li Jinshan, Kou Hongchao, Huang Tingting, Zhou Lian
State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an, 710072, People's Republic of China.
National & Local Joint Engineering Research Center for Precision Thermalforming Technology of Advanced Metal Materials, Xi'an, 710072, People's Republic of China.
J Mater Sci Mater Med. 2015 Sep;26(9):233. doi: 10.1007/s10856-015-5565-5. Epub 2015 Sep 18.
Porous titanium and its alloys are believed to be promising materials for bone implant applications, since they can reduce the "stress shielding" effect by tailoring porosity and improve fixation of implant through bone ingrowth. In the present work, porous Ti6Al4V alloys for biomedical application were fabricated by diffusion bonding of alloy meshes. Compressive mechanical behavior and compatibility in the range of physiological strain rate were studied under quasi-static and dynamic conditions. The results show that porous Ti6Al4V alloys possess anisotropic structure with elongated pores in the out-of-plane direction. For porous Ti6Al4V alloys with 60-70 % porosity, more than 40 % pores are in the range of 200-500 μm which is the optimum pore size suited for bone ingrowth. Quasi-static Young's modulus and yield stress of porous Ti6Al4V alloys with 30-70 % relative density are in the range of 6-40 GPa and 100-500 MPa, respectively. Quasi-static compressive properties can be quantitatively tailored by porosity to match those of cortical bone. Strain rate sensitivity of porous Ti6Al4V alloys is related to porosity. Porous Ti6Al4V alloys with porosity higher than 50 % show enhanced strain rate sensitivity, which is originated from that of base materials and micro-inertia effect. Porous Ti6Al4V alloys with 60-70 % porosity show superior compressive mechanical compatibility in the range of physiological strain rate for cortical bone implant applications.
多孔钛及其合金被认为是骨植入应用的有前景的材料,因为它们可以通过调整孔隙率来降低“应力屏蔽”效应,并通过骨长入改善植入物的固定。在本工作中,通过合金网的扩散连接制备了用于生物医学应用的多孔Ti6Al4V合金。研究了在准静态和动态条件下生理应变率范围内的压缩力学行为和相容性。结果表明,多孔Ti6Al4V合金具有各向异性结构,在平面外方向有细长的孔隙。对于孔隙率为60 - 70%的多孔Ti6Al4V合金,超过40%的孔隙在200 - 500μm范围内,这是适合骨长入的最佳孔径。相对密度为30 - 70%的多孔Ti6Al4V合金的准静态杨氏模量和屈服应力分别在6 - 40 GPa和100 - 500 MPa范围内。准静态压缩性能可以通过孔隙率进行定量调整以匹配皮质骨的性能。多孔Ti6Al4V合金的应变率敏感性与孔隙率有关。孔隙率高于50%的多孔Ti6Al4V合金表现出增强的应变率敏感性,这源于基体材料的应变率敏感性和微惯性效应。孔隙率为60 - 70%的多孔Ti6Al4V合金在皮质骨植入应用的生理应变率范围内表现出优异的压缩力学相容性。