Qin Qixue, Ren Daan, Yu Shouyun
State Key Laboratory of Analytical Chemistry for Life Science, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China.
Org Biomol Chem. 2015 Nov 7;13(41):10295-8. doi: 10.1039/c5ob01725d.
A visible-light-promoted chloramination of olefins is reported. N-Chlorosulfonamides serve as both nitrogen and chlorine sources. These reactions provide a simple, efficient, regioselective, and atom-economical method for the preparation of vicinal haloamine derivatives under mild reaction conditions. A variety of olefins were tolerated, and chloramination products were obtained in good yields.
报道了一种可见光促进的烯烃氯胺化反应。N-氯磺酰胺用作氮源和氯源。这些反应提供了一种在温和反应条件下制备邻位卤代胺衍生物的简单、高效、区域选择性和原子经济性的方法。该反应能耐受多种烯烃，并以良好的产率得到氯胺化产物。
