Adolphe Merkle Institute, University of Fribourg, Chemin des Verdiers 4, 1700, Fribourg, Switzerland.
Department of Chemistry, University of Basel, Klingelbergstrasse 80, 4056, Basel, Switzerland.
Adv Mater. 2015 Nov;27(42):6620-4. doi: 10.1002/adma.201502761. Epub 2015 Sep 29.
Breathable and waterproof membranes that self-seal damaged areas are prepared by modifying a poly(ether ester) membrane with an amphiphilic polymer co-network. The latter swells in water and the gel closes punctures. Damaged composite membranes remain water tight up to pressures of at least 1.6 bar. This material is useful for applications where water-vapor permeability, self-sealing properties, and waterproofness are desired, as demonstrated for a medical cooling device.
通过用两亲聚合物共聚网络对聚醚酯膜进行改性,制备了透气且防水的自密封膜,后者在水中溶胀,凝胶封闭穿孔。受损的复合膜在至少 1.6 巴的压力下保持水密。这种材料可用于需要水蒸气透过率、自密封性能和防水性的应用,例如医疗冷却装置。