London Centre for Nanotechnology, 17-19 Gordon Street London WC1H 0AH, UK.
Department of Chemistry, University College London, London WC1H 0AJ, UK.
Nat Mater. 2016 Jan;15(1):66-71. doi: 10.1038/nmat4449. Epub 2015 Oct 19.
Diffusion across surfaces generally involves motion on a vibrating but otherwise stationary substrate. Here, using molecular dynamics, we show that a layered material such as graphene opens up a new mechanism for surface diffusion whereby adsorbates are carried by propagating ripples in a motion similar to surfing. For water nanodroplets, we demonstrate that the mechanism leads to exceedingly fast diffusion that is 2-3 orders of magnitude faster than the self-diffusion of water molecules in liquid water. We also reveal the underlying principles that regulate this new mechanism for diffusion and show how it also applies to adsorbates other than water, thus opening up the prospect of achieving fast and controllable motion of adsorbates across material surfaces more generally.
表面扩散通常涉及在振动但静止的基底上的运动。在这里,我们使用分子动力学表明,像石墨烯这样的层状材料为表面扩散开辟了一种新的机制,通过这种机制,吸附物可以通过在类似于冲浪的运动中传播的波纹来传递。对于水纳米液滴,我们证明该机制导致极其快速的扩散,比水分子在液态水中的自扩散快 2-3 个数量级。我们还揭示了调节这种扩散新机制的基本原理,并展示了它如何适用于除水以外的其他吸附物,从而为更普遍地实现吸附物在材料表面的快速和可控运动开辟了前景。